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81.
Haitang Yang Zilong Lu Bixiong Bie Zeyu Fu Jianling Yue Xiaozhong Huang 《Ceramics International》2019,45(9):11395-11402
SiCf/PyC/SiC and SiCf/BN/SiC mini-composites comprising single tow SiC fibre-reinforced SiC with chemical vapor deposited PyC or BN interface layers are fabricated. The microstructure evolutions of the mini-composite samples as the oxidation temperature increases (oxidation at 1000, 1200, 1400, and 1600?°C in air for 2?h) are observed by scanning electron microscopy, energy dispersive spectrometry, and X-ray diffraction characterization methods. The damage evolution for each component of the as-fabricated SiCf/SiC composites (SiC fibre, PyC/BN interface, SiC matrix, and mesophase) is mapped as a three-dimensional (3D) image and quantified with X-ray computed tomography. The mechanical performance of the composites is investigated via tensile tests.The results reveal that tensile failure occurs after the delamination and fibre pull-out in the SiCf/PyC/SiC composites due to the volatilization of the PyC interface at high temperatures in the air environment. Meanwhile, the gaps between the fibres and matrix lead to rapid oxidation and crack propagation from the SiC matrix to SiC fibre, resulting in the failure of the SiCf/PyC/SiC composites as the oxidation temperature increases to 1600?°C. On the other hand, the oxidation products of B2O3 molten compounds (reacted from the BN interface) fill up the fracture, cracks, and voids in the SiC matrix, providing excellent strength retention at elevated oxidation temperatures. Moreover, under the protection of B2O3, the SiCf/BN/SiC mini-composites show a nearly intact microstructure of the SiC fibre, a low void growth rate from the matrix to fibre, and inhibition of new void formation and the SiO2 grain growth from room to high temperatures. This work provides guidance for predicting the service life of SiCf/PyC/SiC and SiCf/BN/SiC composite materials, and is fundamental for establishing multiscale damage models on a local scale. 相似文献
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针对传统的小区内开环功率控制算法通常以提升本小区的吞吐量性能为目标,忽略了当前小区用户对邻小区用户同频干扰的问题,为提升边缘用户性能的同时兼顾系统整体性能,提出了一种LTE系统小区间上行联合功率控制(UJPC)算法。该算法采用单基站三扇区为系统模型,以最优化系统吞吐量比例公平函数为目标,首先根据最小信干噪比(SINR)约束值和用户最大发射功率这两个约束条件得到相应的数学优化模型,然后采用连续凸近似的方法求解优化问题得出各个基站所管辖的小区内所有用户的最优发射功率。仿真结果表明,与基准的开环功控方案相比,联合功控方案在保证系统平均频谱利用率的情况下能够较大幅度地提高小区边缘频谱利用率,其最佳性能增益能达到50%。 相似文献
85.
Yuanfang Tao Xin Ji Dr. Jian Zhang Yue Jin Nannan Wang Prof. Yubing Si Prof. Weili Zhao 《Chembiochem : a European journal of chemical biology》2020,21(21):3131-3136
Near-infrared (NIR) fluorescent probes are very significant for detecting cysteine in biological systems. Herein, we report a highly selective and sensitive NIR turn-on fluorescent probe (BDP-NIR) based on BODIPY with large Stokes shift (105 nm) for detecting Cys. We clarified the sensing mechanism based on the different thiol-induced SNAr substitution/rearrangement reaction of the probe with cysteine and homocysteine/glutathione, which leads to the corresponding amino- and thiol-BODIPY dyes with distinct photophysical properties. Moreover, a novel mechanism of fluorescence quenching was demonstrated by density functional theory calculation. The reason for the fluorescence quenching of the probe might be intersystem crossing (from singlet to triplet excited state). Moreover, BDP-NIR had a high linear dynamic range of 0–500 μM, which was promising for detecting cysteine quantificationally. Significantly, BDP-NIR was capable of sensing endogenous cysteine in living cells and in vivo. 相似文献
86.
87.
Xiaopeng Yue Yongjian Xu Nina Gou Hongkui Li 《Polymer-Plastics Technology and Engineering》2015,54(6):639-646
A long fatty side chain was introduced into the macromolecule of hydroxyethyl cellulose (HEC) via esterification reaction. The hydrophobicity of hydroxyethyl cellulose lauric acid ester (HECLAE) was enhanced in comparison with HEC. The obtained HECLAE was used as macromolecular coupling agent in poly (butylene succinate)/wood flour composites and exhibited a positive influence on improving the mechanical performance of composites. Besides, HECLAE plays a role as a hydrophobic agent in composites. A significant increase in storage modulus (E’) was observed upon the incorporation of treated wood flour. SEM images showed that the dispersion of treated wood flour in PBS matrix was improved. 相似文献
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89.
朱岳 《合成材料老化与应用》2020,49(1):36-39
以膨润土片层结构做模板,将银氨溶液与改性膨润土进行离子交换反应,通过光还原法制备得到了纳米银插层膨润土抗菌剂。通过高分辨透射电镜、能谱分析测试表征纳米银插层膨润土抗菌剂的结构与成分,并测试抗菌性能和白度变化。结果表明:纳米银插层膨润土抗菌剂的膨润土片层中夹插有球形纳米银,纳米银颗粒的主要粒径为2-8 nm,其中小部分粒径为8-17 nm,这种独特的模板结构确保纳米银抗菌剂结构稳定和性能稳定。纳米银插层膨润土抗菌剂中纳米银含银量为1.04wt%,有优异的抗菌性能,对金黄色葡萄球菌和大肠杆菌的最小抑菌浓度(MIC)分别为50μg/mL。纳米银插层膨润土抗菌剂具有颜色稳定性和持久抗菌性。 相似文献
90.
采用双转子连续混炼挤出机并通过熔融共混法制备了碳纤维(CF)增强聚苯硫醚(PPS)复合材料,并对其微观形貌、动态力学性能、力学性能和导电性能进行了研究,且对相关的影响因素进行了分析。结果表明,适当降低挤出机转子转速、提高CF含量可以改善PPS/CF复合材料的力学性能和导电性能;当转子转速为200r/min时,采用含量为20 % (质量分数,下同)的CF制得的PPS/CF复合材料的冲击强度达到49.94 J/m,体积电阻率达到60.65 Ω·cm,均优于纯PPS。 相似文献